ISSN 2394-5125
 

Research Article 


SYNTHESIS OF AROMATIC ACETYLENE ALCOHOLS ON THE BASIS OF VARIOUS ALDEHYDES IN THE CATALYTIC SYSTEM (OIPR)4 ZNET2/TI(OIPR)4

Abdurakhmanova Saida, Ziyadullaev Odiljon, Ikramov Abduvahob, Saliyeva Muyassar.

Abstract
Acetic aldehyde,benzaldehyde and cyclohexonal investiged for the first time, ZnEt2/Ti(OiPr)4catalysis with phenylacetylene reaction of enantioselective alkynilation. The nature of seluted aldehydes, spatial structure and optical activity of their molecules and impact of productivity of sequence was observed. Efficiency of formation acetylene alcohol. Efficiency and course of chemical reaction in the process of formation acetylene alcohol affection of temperature, reaction duration, solvents, catalysts and constituents, their number and nature effects, reaction kinetics and mechanisms was investigated in consequence of theoretical and chemical methods, quantum chemical calculations were determined based on modern computer technologies. Based on the results obtained to increase the acetylene alcohol production, reduce the amount of supplementary and intermediate products, the most favorable conditions were found.

Key words: phenylacetylene, benzaldehyde, alkynylation reaction, acetylene alcohols, catalysts, selectivity, reaction mechanism, product yields


 
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Pubmed Style

Abdurakhmanova Saida, Ziyadullaev Odiljon, Ikramov Abduvahob, Saliyeva Muyassar. SYNTHESIS OF AROMATIC ACETYLENE ALCOHOLS ON THE BASIS OF VARIOUS ALDEHYDES IN THE CATALYTIC SYSTEM (OIPR)4 ZNET2/TI(OIPR)4. JCR. 2020; 7(19): 1488-1499. doi:10.31838/jcr.07.19.180


Web Style

Abdurakhmanova Saida, Ziyadullaev Odiljon, Ikramov Abduvahob, Saliyeva Muyassar. SYNTHESIS OF AROMATIC ACETYLENE ALCOHOLS ON THE BASIS OF VARIOUS ALDEHYDES IN THE CATALYTIC SYSTEM (OIPR)4 ZNET2/TI(OIPR)4. http://www.jcreview.com/?mno=106433 [Access: July 21, 2020]. doi:10.31838/jcr.07.19.180


AMA (American Medical Association) Style

Abdurakhmanova Saida, Ziyadullaev Odiljon, Ikramov Abduvahob, Saliyeva Muyassar. SYNTHESIS OF AROMATIC ACETYLENE ALCOHOLS ON THE BASIS OF VARIOUS ALDEHYDES IN THE CATALYTIC SYSTEM (OIPR)4 ZNET2/TI(OIPR)4. JCR. 2020; 7(19): 1488-1499. doi:10.31838/jcr.07.19.180



Vancouver/ICMJE Style

Abdurakhmanova Saida, Ziyadullaev Odiljon, Ikramov Abduvahob, Saliyeva Muyassar. SYNTHESIS OF AROMATIC ACETYLENE ALCOHOLS ON THE BASIS OF VARIOUS ALDEHYDES IN THE CATALYTIC SYSTEM (OIPR)4 ZNET2/TI(OIPR)4. JCR. (2020), [cited July 21, 2020]; 7(19): 1488-1499. doi:10.31838/jcr.07.19.180



Harvard Style

Abdurakhmanova Saida, Ziyadullaev Odiljon, Ikramov Abduvahob, Saliyeva Muyassar (2020) SYNTHESIS OF AROMATIC ACETYLENE ALCOHOLS ON THE BASIS OF VARIOUS ALDEHYDES IN THE CATALYTIC SYSTEM (OIPR)4 ZNET2/TI(OIPR)4. JCR, 7 (19), 1488-1499. doi:10.31838/jcr.07.19.180



Turabian Style

Abdurakhmanova Saida, Ziyadullaev Odiljon, Ikramov Abduvahob, Saliyeva Muyassar. 2020. SYNTHESIS OF AROMATIC ACETYLENE ALCOHOLS ON THE BASIS OF VARIOUS ALDEHYDES IN THE CATALYTIC SYSTEM (OIPR)4 ZNET2/TI(OIPR)4. Journal of Critical Reviews, 7 (19), 1488-1499. doi:10.31838/jcr.07.19.180



Chicago Style

Abdurakhmanova Saida, Ziyadullaev Odiljon, Ikramov Abduvahob, Saliyeva Muyassar. "SYNTHESIS OF AROMATIC ACETYLENE ALCOHOLS ON THE BASIS OF VARIOUS ALDEHYDES IN THE CATALYTIC SYSTEM (OIPR)4 ZNET2/TI(OIPR)4." Journal of Critical Reviews 7 (2020), 1488-1499. doi:10.31838/jcr.07.19.180



MLA (The Modern Language Association) Style

Abdurakhmanova Saida, Ziyadullaev Odiljon, Ikramov Abduvahob, Saliyeva Muyassar. "SYNTHESIS OF AROMATIC ACETYLENE ALCOHOLS ON THE BASIS OF VARIOUS ALDEHYDES IN THE CATALYTIC SYSTEM (OIPR)4 ZNET2/TI(OIPR)4." Journal of Critical Reviews 7.19 (2020), 1488-1499. Print. doi:10.31838/jcr.07.19.180



APA (American Psychological Association) Style

Abdurakhmanova Saida, Ziyadullaev Odiljon, Ikramov Abduvahob, Saliyeva Muyassar (2020) SYNTHESIS OF AROMATIC ACETYLENE ALCOHOLS ON THE BASIS OF VARIOUS ALDEHYDES IN THE CATALYTIC SYSTEM (OIPR)4 ZNET2/TI(OIPR)4. Journal of Critical Reviews, 7 (19), 1488-1499. doi:10.31838/jcr.07.19.180





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